The aim of the current work is the in-situ characterization of carbon-based electrode materials using innovative electrochemical methodologies to investigate the so-called ‘ distributed capacitance phenomena ’ verified in the time domain using the single-step chronoamperometry (SSC) and the galvanostatic charge–discharge (GCD) techniques.
The major contribution of this work is the precise detection and quantitative analysis of the so-called ‘ distributed capacitance phenomenon ’ verified in the time domain using the chronoamperometric (SSC) and chronopotentiometric (GCD) techniques. MWCNT-based electrode materials were used in the symmetric coin cell.
The distributed capacitance relationship ( Cdist. vs t) can be experimentally accessed from the discharging curves using a derivative analysis: (17) C distr. = dQ dU = I dU / dt where I = dQ / dt, and dU / dt is the derivative ( numeric differentiation) of the discrete available data.
Despite these considerations, one has the major contribution to the total capacitance ( Ctotal = CEDL + Cads) for the different symmetric devices was given by the pronounced redox-activity of the oxygenated surface groups present in the different electrodes.
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